Mathias DELPORTE-PÉBAY PhD defense
Hexahelicenic complexes of gold and platinum: influence of the metals on the structural and chiroptical properties
Lunedì 13 ottobre 2025, 09:00Passato
Organometallics: Materials and Catalysis (OMC) team
Abstract:
At the molecular scale, chirality gives rise to specific light–matter interactions known as chiroptical properties. Among these, circularly polarized luminescence (CPL) can be exploited in circularly polarized OLEDs, enabling the reduction of energy losses associated with the use of anti-glare filters. This PhD work focuses on the synthesis and investigation of chiral helicenic bimetallic complexes incorporating two gold or platinum metal centers. The molecular design was conceived to promote metal–metal interactions, in order to study their influence on the structural, photophysical, and chiroptical properties. The objective was to develop complex bimetallic architectures capable of emitting circularly polarized light in the near-infrared region. Some of these architectures exhibited unprecedented asymmetric molecular organizations and enhanced circularly polarized phosphorescence properties.
Jury:
- Franck Camerel, Université de Rennes, ISCR / Examinateur
- Elsa Caytan, Université de Rennes, ISCR / Examinatrice
- Jeanne Crassous, Université de Rennes, ISCR / Directrice de thèse
- Denis Frath, ENS Lyon / Rapporteur
- Guillaume Vives, Sorbonne université / Rapporteur
Contact: Jeanne Crassous, jeanne.crassous@univ-rennes.fr
